导语

  

内容提要

  

    化学链燃烧技术可以实现二氧化碳的低能耗捕捉，具有较好的商业化前景。刘方、杨丽著的《化学链载氧体\载炭体开发及反应器尺度模拟(英文版)》对化学链燃烧技术及发展现状做了详细介绍，对该技术中关键要素载氧体，特别是针对铁基载氧体的开发着重进行了讲解，提出了铁基载氧体改性的方法，揭示了反应促进机理。最后，基于化学链放大技术中的难题，以实例出发，总结了建模放大的规律，实现了化学链技术的规模化放大。本书对指导二氧化碳捕捉、载氧体的开发及污染物减排具有较好的参考价值，对与商业化减排二氧化碳技术的开发具有较好的指导作用。

1  Introduction
  1.1  Background
  1.2  CO2 capture and disposal
  1.3  Chemical looping combustion introduction
  1.4  CLC combined power generation
2  Development of Oxygen Carrier
  2.1  Oxygen carrier introduction
  2.2  Performance evaluation
  2.3  OC screening
  2.4  Thermodynamic analysis
  2.5  Iron oxide based OC review
  2.6  Scale modeling
  2.7  Objectives
3  Experimental Setup and Methods
  3.1  TGA/MS measurement
  3.2  Bench scale CLC setup
  3.3  Microscopic imaging
  3.4  Mechanical strength
  3.5  Surface area measurement
  3.6  XRD
  3.7  Raman spectroscopy
4  Performance of Synthesized Oxygen Carrier
  4.1  Synthetic oxygen carrier production
  4.2  Effect of CeO2 additive on the physical properties
  4.3  Reactivity
  4.4  Reaction mechanism
5  Development of Low Cost Ilmenite Oxygen Carriers
  5.1  Ilmenite OC review
  5.2  Experiment and menthodology
  5.3  Results and discussion
  5.4  Conclusion
6  Reaction Kinetics Study
  6.1  Reaction kinetics study
  6.2  Reaction kinetics of ilmenite OC
  6.3  Discussion and conclusion
7  Scale-up Study
  7.1  Governing equations
  7.2  Experiment
  7.3  Results and discussion
  7.4  Conclusion
8  Extended Chemical Looping Technology for Continuous High Purity
  Hydrogen Production
  8.1  Overview of hydrogen production
  8.2  Methane decomposition catalysts
  8.3  Chemical looping hydrogen production process
  8.4  Experimental setup and methods
  8.5  Activated carbon catalyst {or high purity hydrogen production
  8.6  Cyclic performance of AC catalyst
  8.7  Catalytic activity dominating parameters  
  8.8  Conclusion
9  Regeneration of Activated Carbon Carrier with Respect to Activity and
  Heat Supply
  9.1  Reactions
  9.2  Deep regeneration using O2 or CO2
  9.3   H2O+O2 as regeneration agent
  9.4  Characterization o{ the regenerated AC
  9.5  Heat and mass balance analysis
  9.6  Conclusion
10  Root Cause Analysis of Catalytic Activity
  10.1  Catalytic performance of AC and CB ..
  10.2  Morphology evolution
  10.3  Crystalline phase
  10.4  Root cause analysis
  10.5  Conclusion
11  Conclusions and Future Work
Nomenclature
References