导语

  

内容提要

  

    The textbook is divided into eight chapters.In the introduction,the basic concept of polymer,classification and nomenclature of polymer,reaction type of polymer,development history of polymer and application of polymer are introduced in brief.In the next six chapters,free radical polymerization,free radical copolymerization,ionic polymerization,step polymerization,ring-opening polymerization and chemical reactions of polymers are introduced in detail.The implementation methods of polymerization are introduced systematically in the last chapter.The new words and terminology are noted in Chinese in detail,and the large exercises are attached at the end of each chapter,which is helpful for the students who are new to polymer chemistry to study smoothly.
    This book is used as the textbook for colleges and universities.It is suitable for the major of Polymer Materials and Engineering,Material Chemistry,Material Science and Engineering,New Energy Materials and Devices,New Energy Materials and Engineering,Chemical Engineering and Technology,Applied Chemistry in engineering,Chemistry,Organic Chemistry,Analytical Chemistry,Polymer Chemistry and Polymer Physics in science,and Chemistry in normal colleges.It can also be used as the reference for junior college,scientific researchers and production technicians.
    《Polymer Chemistry(双语教学用)》共分8章。首先在绪论中介绍了聚合物的基本概念、聚合物的分类和命名、聚合物的反应类型、聚合物的发展历程、聚合物的应用等。接下来6章分别就自由基聚合、自由基共聚、离子聚合、逐步聚合、开环聚合、聚合物的化学反应进行详细介绍。最后1章较系统地介绍聚合实施方法。书中对专业生词和专业术语做了较详细的中文注解，另每章后都附有习题，有利于初接触到高分子化学的学生顺利学习。
    本书适合作为高等院校教材，适用于工科的高分子材料与工程、材料化学、材料科学与工程、新能源材料与器件、新能源材料与工程、化学工程与工艺和应用化学专业，理科的化学、有机化学、分析化学、高分子化学及物理专业，师范院校的化学专业。也可供大专院校师生以及科研人员和生产技术人员参考。

Chapter 1 INTRODUCTION
  1.1  BASIC CONCEPTS AND DEFINITIONS
    1.1.1  Monomers and Polymers
    1.1.2  Structural Unit and Repeating Unit
    1.1.3  Dimers,Trimers and Oligomers
    1.1.4  Linear Polymers
    1.1.5  Branched Polymers
    1.1.6  Crosslinked Polymers
    1.1.7  Stars and Dendrimers
    1.1.8  Ladder Polymers
    1.1.9  Copolymers
  1.2  AVERAGE MOLECULAR WEIGHT AND DISTRIBUTION
  1.3  TYPES OF POLYMERS AND POLYMERIZATIONS
    1.3.1  Condensation Reactions
    1.3.2  Addition Reactions
    1.3.3  Ring-opening Polymerizations
  1.4  POLYMERIZATION MECHANISM
    1.4.1  Step Polymerization
    1.4.2  Chain Polymerization
    1.4.3  Comparison of Step and Chain Polymerization
  1.5  NOMENCLATURE OF POLYMERS
    1.5.1  Nomenclature Based on Source
    1.5.2  Nomenclature Based on Structure (Non-IUPAC)
    1.5.3  Trade Name
    1.5.4  IUPAC Structure-Based Nomenclature System
  1.6  A BRIEF HISTORY OF SYNTHETIC POLYMERS
    1.6.11  838-1930's
    1.6.21  930-1945's
    1.6.31  945-1960's
    1.6.41  960-1980's
    1.6.51  980-2000's
    1.6.62  000-2018's
    1.6.7  Prospect of Polymer Materials
  1.7  HISTORY OF NOBEL PRIZES FOR POLYMER SCIENCE
  1.8  APPLICATION OF POLYMERS
  Exercises 1
Chapter 2 FREE-RADICAL POLYMERIZATION
  2.1  INTRODUCE
    2.1.1  Initiators
    2.1.2  Monomers
    2.1.3  Solvents and Systems
  2.2  INITIATION
    2.2.1  Initiation by Thermal Decomposition of Initiators
    2.2.2  Initiation by Redox Reactions
    2.2.3  Initiation by Photolytic and Ionizing Radiation
    2.2.4  Reactions of Initiator Radicals with Monomers
  2.3  RADICAL CHAIN PROPAGATION
  2.4  CHAIN TRANSFER REACTIONS
  2.5  FREE RADICAL CHAIN TERMINATION
  2.6  KINECTICS OF FREE RADICAL POLYMERIZATION
    2.6.1  Approximations
    2.6.2  Steady-state Concentrations of the Propagating Radicals
    2.6.3  Theoretic Rate of Polymerization
  2.7  AVERAGE KINETIC CHAIN LENGTH
  2.8  AVERAGE DEGREE OF POLYMERIZATION AND AVERAGE MOLECULAR WEIGHT
  2.9  EFFECT OF CHAIN TRANSFER ON AVERAGE DEGREE OF POLYMERIZATION
  2.10  DEPENDENCE OF THE DEGREE OF POLYMERIZATION ON TEMPERATURE
  2.11  DISTRIBUTION OF MOLECULAR WEIGHT
    2.11.1  Disproportionation Termination
    2.11.2  Combination Termination
  2.12  INHIBITOR AND RETARDER
  Exercises 2
Chapter 3 FREE-RADICAL COPOLYMERIZATION
  3.1  TYPES AND NAMENCLATURE OF COPOLYMERS
  3.2  REACTIVITY RATIO AND COPOLYMER COMPOSITION EQUATION
  3.3  COPOLYMERIZATION BEHAVIOR
    3.3.1  Ideal Copolymerization
    3.3.2  Alternating Copolymerization
    3.3.3  Non-ideal Copolymerization
    3.3.4  "Block" Copolymerization
  3.4  EXPERIMENTAL DETERMINATION OF ACTIVITY RATIOS
  3.5  VARIATION OF COPOLYMER COMPOSITION WITH CONVERSION
  3.6  EFFECT OF MONOMER STRUCTURE ON REACTIVITY
    3.6.1  Conjugation Effect
    3.6.2  Polarity Effect
    3.6.3  Steric Effect
  3.7  Q-e EQUATIONS
  3.8  DISTRIBUTION OF MONOMERS IN A COPOLYMER
  Exercises 3
Chapter 4 IONIC POLYMERIZATION
  4.1  ANIONIC POLYMERIZATION
    4.1.1  Initiators for Anionic Polymerization
    4.1.2  Monomers for Anionic Polymerization
    4.1.3  Solvents
    4.1.4  The Mechanism of Anionic Polymerization (General)
    4.1.5  Living Polymers and Copolymerization
  4.2  COORDINATION POLYMERIZATION
    4.2.1  Ziegler-Natta Catalyst
    4.2.2  Composition of the Catalyst
    4.2.3  Polymerization Mechanism
  4.3  CATIONIC POLYMERIZATION
    4.3.1  Initiators for Cationic Polymerization
    4.3.2  Monomers for Cationic Polymerization
    4.3.3  The Mechanism of Cationic Polymerization
    4.3.4  Special Characteristics of Classical Cationic Polymerizations
  4.4  KINETICS OF IONIC POLYMERIZATION
    4.4.1  Anionic Polymerization
    4.4.2  Cationic Polymerization
  Exercises 4
Chapter 5 STEP POLYMERIZATION
  5.1  INTRODUCTION
    5.1.1  Types of Condensation Reactions
    5.1.2  Requirements for High Molecular Weight
  5.2  SPECIFIC CONDENSATION POLYMERIZATIONS
    5.2.1  Linear Polyesters
    5.2.2  Branched and Crosslinked Polyesters
    5.2.3  Polycarbonates
    5.2.4  Polyamides (nylons)
  5.3  KINETICS OF STEP POLYMERIZATION
    5.3.1  Equal Reactivity of Functional Groups
    5.3.2  Rate of Polymerization Reactions
    5.3.3  Kinetics of Polyesterification
  5.4  TIME DEPENDENCE OF THE AVERAGE DEGREE OF POLYMERIZATION
  5.5  MOLECULAR WEIGHT DISTRIBUTIONS
  5.6  EFFECT OF NONSTOICHIOMETRIC REACTANT RATIOS
  5.7  BRANCHED AND CROSSLINKED CONDENSATION POLYMERS
  5.8  THE METHOD OF STEP POLYMERIZATION
    5.8.1  Melt Condensation Polymerization
    5.8.2  Solution Polymerization
    5.8.3  Interfacial Polycondensation
    5.8.4  Solid Phase Polycondensation
  5.9  RANDOM PREPOLYMERS AND STRUCTURE PREPOLYMERS
    5.9.1  Random Performed Polymers
    5.9.2  Structure Prepolymers
  Exercises 5
Chapter 6 RING-OPENING POLYMERIZATION
  6.1  INTRODUCTION
  6.2  CHARACTERISTICS OF RING-OPENING POLYMERIZATION
  6.3  POLYMERIZATION ABILITY OF CYCLIC MONOMERS
  6.4  THERMODYNAMICS OF RING-OPENING POLYMERIZATION OF CYCLOALKANES
  6.5  THERMODYNAMIC AND KINETIC CHARACTERISTICS OF CYCLOALKANE POLYMERIZATION
  6.6  IMPORTANT RING-OPENING POLYMERIZATION IN INDUSTRY
    6.6.1  Cyclic Ether
    6.6.2  Cationic Ring-opening Polymerization of Carbonyl Compounds and Acetals
    6.6.3  Ring-opening Polymerization of Cyclic Amides
    6.6.4  Cyclosiloxane
  Exercises 6
Chapter 7 REACTIONS OF SYNTHETIC POLYMERS
  7.1  REACTIONS INVOLVING THE MAIN CHAIN
    7.1.1  Addition Reactions
    7.1.2  Reactions that Generate Skeletal Unsaturation
    7.1.3  Hydrolytic Chain Cleavage
    7.1.4  Enzymatic Degradation of Synthetic Polymers
    7.1.5  Oxidation Reactions
    7.1.6  High Temperature Degradation Reactions
    7.1.7  Electron Beam Depolymerization
  7.2  REACTIONS INVOLVING THE SIDE GROUPS
    7.2.1  Principles of Polymer Reactivity
    7.2.2  Hydrolysis of Side Group Structures
    7.2.3  Chloromethylation of Polystyrene
  7.3  GRAFT POLYMER FORMATION
  7.4  CROSS-LINKING REACTION
  7.5  SURFACE REACTIONS OF POLYMERS
    7.5.1  Surface Fluorination
    7.5.2  Surface Nitrification and Sulfonation
    7.5.3  Surface Oxidation
  Exercises 7
Chapter 8 METHODS OF POLYMERIZATION
  8.1  BULK (MASS) POLYMERIZATION
  8.2  SOLUTION POLYMERIZATION
  8.3  SUSPENSION POLYMERIZATION
  8.4  EMULSION POLYMERIZATION
    8.4.1  Description of Process
    8.4.2  Quantitative Aspects
    8.4.3  Other Characteristics of Emulsion Polymerization
    8.4.4  Soap-Free Emulsion Polymerization
    8.4.5  Inverse Emulsion Polymerization
    8.4.6  Miniemulsion Polymerization
    8.4.7  Microemulsion Polymerization
    8.4.8  Seed Emulsion Polymerization
    8.4.9  Core-shell Emulsion Polymerization
    8.4.10  Dispersion Polymerization
    8.4.11  Living Radical Polymerization
  Exercises 8
REFERENCE